Shorter still: compressing C-C single bonds.
نویسندگان
چکیده
How short can a C-C single bond get? The bonding in a set of molecules that are related structurally to previously synthesized or theoretically examined systems with short C-C bonds is investigated. According to calculations, a single C-C bond could be compressed to 1.313 Å! To the best of our knowledge, this is the shortest single C-C bond reported to date. This shortening is a consequence of a change in the C-C-C bond angle, θ, to minimize strain in the cages and an effort to offset the tension in the surrounding bridges.
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عنوان ژورنال:
- Organic letters
دوره 12 18 شماره
صفحات -
تاریخ انتشار 2010